Description of strontium precipitation in highly concentrated nitric acid

نویسندگان

چکیده

The precipitation of strontium in highly concentrated nitric acid is often used standard radiochemical methods for 90Sr separation. In this work, the description Sr behavior such conditions was studied point speciation simulation. Standard method based on Phreeqc software considered but two problems underlined limits approach to study process: inappropriate ionic strength correction model (for I > 10 M) and particular dissociation acid. To overcome these issues, a multipurpose-fitting routine, Minuit, fit chemical parameters. A polynomial expression also added order take into account dissociation. This alternative proved successful calculate precipitate Comparison made with results obtained Design Experiment methodology.

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ژورنال

عنوان ژورنال: Journal of Radioanalytical and Nuclear Chemistry

سال: 2022

ISSN: ['0236-5731', '1588-2780']

DOI: https://doi.org/10.1007/s10967-022-08387-x